'Pancake' bonding: a charge-density perspective
نویسندگان
چکیده
منابع مشابه
Intramolecular Pancake Bonding in Helical Structures.
We show that diradicaloid helical conjugated molecules can display strong through-space bonding interactions. These interactions are analogous to π-stacking pancake bonding widely observed for dimers and other aggregates of stable π-conjugated radicals. We show that these multicenter interactions can have a significant stabilizing effect, but they depend in subtle ways on the specific overlap a...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2018
ISSN: 2053-2733
DOI: 10.1107/s2053273318090630